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      Economics & carbon dioxide avoidance cost of methanol production based on renewable hydrogen and recycled carbon dioxide – power-to-methanol

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          Abstract

          The cost of producing “green” methanol ( vs. fossil production) based on renewable energy, H 2 and CO 2 is presented.

          Abstract

          The synthesis of sustainable methanol based on renewable electricity generation, sustainable hydrogen (H 2) and recycled carbon dioxide (CO 2) represents an interesting sustainable solution to integrated renewable energy storage and platform chemical production. However, the business case for this electricity based product (denoted hereafter as eMeOH) under current market conditions ( e.g. vs. conventional fossil methanol (fMeOH) production cost) and the appropriate implementation scenarios to increase platform attractiveness and adoption have to be highlighted. The aim of the following study was to perform a dynamic simulation and calculation of the cost of eMeOH production (where electricity is generated at a wind park in Germany), with comparison made to grid connected scenarios. Consideration of these scenarios is made with particular respect to the German energy market and potential for the reduction in fees/taxes ( i.e. for electrolyser systems). This evaluation and indeed the results can be viewed in light of European Union efforts to support the implementation of such technologies. In this context, CO 2 is sourced from EU relevant sources, namely a biogas or ammonia plant, the latter profiting from the resulting credit arising from CO 2 certificate trading. Variation in electricity cost and the CO 2 certificate price (in the presented sensitivity study) demonstrate a high cost reduction potential. Under the energy market conditions of Germany it is found that eMeOH production costs vary between €608 and 1453 per tonne based on a purely grid driven scenario, whilst a purely wind park supplied scenario results in €1028–1067 per tonne. The reported results indicate that the eMeOH production cost in Germany is still above the present (although variable) market price, with the economical evaluation indicating that electrolyser and H 2 storage represent the lion share of investment and operational cost. Substitution of fMeOH results in CO 2 avoidance costs between €365 and 430 per tonne of CO 2eq avoided for green methanol produced in Germany. The presented assessment indicates that the eMeOH production cost in Germany will reach market parity in ca. 2030–2035 with the price for the avoidance of CO 2eq turning from a cost to a benefit at around the same time. Optimistically, the cost is predominantly influenced by rapidly reducing renewable electricity costs as is already the case in South American and Arabic countries offering the potential for methanol production at a cost of <€500 per tonne.

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          Most cited references65

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          Carbon capture and storage update

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            Using carbon dioxide as a building block in organic synthesis.

            Carbon dioxide exits in the atmosphere and is produced by the combustion of fossil fuels, the fermentation of sugars and the respiration of all living organisms. An active goal in organic synthesis is to take this carbon--trapped in a waste product--and re-use it to build useful chemicals. Recent advances in organometallic chemistry and catalysis provide effective means for the chemical transformation of CO₂ and its incorporation into synthetic organic molecules under mild conditions. Such a use of carbon dioxide as a renewable one-carbon (C1) building block in organic synthesis could contribute to a more sustainable use of resources.
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              Is Open Access

              Future cost and performance of water electrolysis: An expert elicitation study

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                Author and article information

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                Journal
                SEFUA7
                Sustainable Energy & Fuels
                Sustainable Energy Fuels
                Royal Society of Chemistry (RSC)
                2398-4902
                2018
                2018
                : 2
                : 6
                : 1244-1261
                Affiliations
                [1 ]Fraunhofer Institute for Solar Energy Systems ISE
                [2 ]79110 Freiburg
                [3 ]Germany
                [4 ]Karlsruhe Institute of Technology (KIT)
                [5 ]76131 Karlsruhe
                Article
                10.1039/C8SE00032H
                f4b63fc9-880c-47a6-8b17-8f98fefa9341
                © 2018

                http://rsc.li/journals-terms-of-use

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