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      PLUS-M: a Porous Liquid-metal enabled Ubiquitous Soft Material

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          Abstract

          Liquid metal transforms into a porous structure and floats on the water surface with heating.

          Abstract

          A Porous Liquid-metal enabled Ubiquitous Soft Material (PLUS-M) was fabricated through loading chemically reactive iron nanoparticles into eutectic gallium–indium alloys (EGaIn), whose porosity and shape could be easily regulated via remote control. Such a PLUS-M could expand to a surprisingly large magnitude in a short time, say seven times its original volume, and generate adjustable closed cell foams inside. Owing to this unique property, the density of the PLUS-M can be easily controlled, allowing the PLUS-M to float on water or even pull up underwater heavy objects above the surface when subjected to heating. What's more, this porous material can transform between liquid and solid states through controlling the oxidation level of gallium using methods like heating and stirring. The reversible transformation between the solid porous structure and liquid state could be achieved more than 100 times without obvious performance degradation.

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          Most cited references19

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          A liquid metal reaction environment for the room-temperature synthesis of atomically thin metal oxides.

          Two-dimensional (2D) oxides have a wide variety of applications in electronics and other technologies. However, many oxides are not easy to synthesize as 2D materials through conventional methods. We used nontoxic eutectic gallium-based alloys as a reaction solvent and co-alloyed desired metals into the melt. On the basis of thermodynamic considerations, we predicted the composition of the self-limiting interfacial oxide. We isolated the surface oxide as a 2D layer, either on substrates or in suspension. This enabled us to produce extremely thin subnanometer layers of HfO2, Al2O3, and Gd2O3 The liquid metal-based reaction route can be used to create 2D materials that were previously inaccessible with preexisting methods. The work introduces room-temperature liquid metals as a reaction environment for the synthesis of oxide nanomaterials with low dimensionality.
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            Is Open Access

            Light-driven liquid metal nanotransformers for biomedical theranostics

            Room temperature liquid metals (LMs) represent a class of emerging multifunctional materials with attractive novel properties. Here, we show that photopolymerized LMs present a unique nanoscale capsule structure characterized by high water dispersibility and low toxicity. We also demonstrate that the LM nanocapsule generates heat and reactive oxygen species under biologically neutral near-infrared (NIR) laser irradiation. Concomitantly, NIR laser exposure induces a transformation in LM shape, destruction of the nanocapsules, contactless controlled release of the loaded drugs, optical manipulations of a microfluidic blood vessel model and spatiotemporal targeted marking for X-ray-enhanced imaging in biological organs and a living mouse. By exploiting the physicochemical properties of LMs, we achieve effective cancer cell elimination and control of intercellular calcium ion flux. In addition, LMs display a photoacoustic effect in living animals during NIR laser treatment, making this system a powerful tool for bioimaging.
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              • Article: not found

              Liquid metal enabled pump.

              Small-scale pumps will be the heartbeat of many future micro/nanoscale platforms. However, the integration of small-scale pumps is presently hampered by limited flow rate with respect to the input power, and their rather complicated fabrication processes. These issues arise as many conventional pumping effects require intricate moving elements. Here, we demonstrate a system that we call the liquid metal enabled pump, for driving a range of liquids without mechanical moving parts, upon the application of modest electric field. This pump incorporates a droplet of liquid metal, which induces liquid flow at high flow rates, yet with exceptionally low power consumption by electrowetting/deelectrowetting at the metal surface. We present theory explaining this pumping mechanism and show that the operation is fundamentally different from other existing pumps. The presented liquid metal enabled pump is both efficient and simple, and thus has the potential to fundamentally advance the field of microfluidics.
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                Author and article information

                Journal
                MHAOAL
                Materials Horizons
                Mater. Horiz.
                Royal Society of Chemistry (RSC)
                2051-6347
                2051-6355
                2018
                2018
                : 5
                : 2
                : 222-229
                Affiliations
                [1 ]Department of Biomedical Engineering, School of Medicine, Tsinghua University
                [2 ]Beijing 100084
                [3 ]China
                [4 ]Beijing Key Lab of Cryo-Biomedical Engineering and Key Lab of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences
                [5 ]Beijing 100190
                Article
                10.1039/C7MH00989E
                ca3854e9-01db-4514-be9a-eb87cfd59a52
                © 2018

                http://rsc.li/journals-terms-of-use

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