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      Selbstorganisation zweizähniger Liganden für die kombinatorische homogene Katalyse auf der Basis eines AT-Basenpaar-Modells

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      Angewandte Chemie
      Wiley

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          Hydrogen bonding as a construction element for bidentate donor ligands in homogeneous catalysis: regioselective hydroformylation of terminal alkenes.

          A new concept for the construction of bidentate ligands for homogeneous metal complex catalysis is described. The concept relies on the self-assembly of monodentate ligands through hydrogen bonding. As a prototype of such systems, 6-diphenylphosphanyl-2-pyridone (6-DPPon) was shown to form a chelate in the coordination sphere of a transition metal center through unusual pyridone/hydroxypyridine hydrogen bonding (X-ray). This hydrogen bonding stays intact in a catalytic reaction as proven upon highly regioselective hydroformylation of terminal alkenes. Regioselectivities and reactivities observed rank the 6-DPPon/rhodium system among the most active and regioselective catalysts for n-selective hydroformylation of terminal alkenes.
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            Recent Advances on Chemo-, Regio- and Stereoselective Hydroformylation

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              Combinatorial libraries of chiral ligands for enantioselective catalysis.

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                Author and article information

                Journal
                Angewandte Chemie
                Angewandte Chemie
                Wiley
                00448249
                March 04 2005
                March 04 2005
                February 09 2005
                : 117
                : 11
                : 1666-1669
                Article
                10.1002/ange.200462499
                31ce491c-ac77-46ef-8bfa-a83f1174d667
                © 2005

                http://doi.wiley.com/10.1002/tdm_license_1.1

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